Why does a battery weaken in the cold?
January in New Brunswick, -20 °C. The battery blower spent the night in the shed, pack on, and still shows its bars; squeeze the trigger and the impeller starts, groans and stalls. On the chainsaw, the display goes dark the moment the chain bites. Brought inside for an hour, the same pack clears the porch.
What is it missing outside, what comes back in the warm, and what would not come back?
Show the answer
The answer
Cold does not empty the cell, it slows it down. Its open-circuit voltage barely moves between 20 °C and -20 °C, a few millivolts per cell, twenty at most: the bars stay lit. What rises is the internal resistance; under the tool’s current, the IR drop eats the terminal voltage.
A 56 V, 5 Ah pack, fourteen groups of two cells (14S2P) at 20 mΩ warm: 0.14 Ω, plus strips, BMS and contacts, 0.17 Ω. At 30 A, a 5 V drop: the tool runs. At -20 °C, a lithium-ion cell resists three to five times more (more still for an energy cell): 0.7 Ω, a 20 V drop, 36 V at the terminals, 2.6 V per group. The BMS or the controller cuts out below 2.5 to 3 V, before the current even settles: the tool stalls, the display goes dark. Release the trigger and the bars come back.
What comes back in the warm: the resistance, as soon as the cell warms up; discharging in the cold leaves no mark. What does not come back: a charge below 0 °C. Lithium ions that no longer enter the graphite plate out on it as metal: capacity lost for good, a deposit that can pierce the separator. A serious charger refuses below 0 to 5 °C.
Teacher’s note
The question is meant to show the cell of target 5, ions inside, electrons outside, and that cold hinders only the former. Copper, for its part, conducts better cold, 0.4% per degree. The ions slow down: in the electrolyte, the organic carbonates of lithium-ion or the potassium hydroxide paste of the alkaline, which thickens; then at the interface, where the electrode reaction follows Arrhenius. An alkaline AA gains 40% resistance per ten degrees colder; lithium-ion, little down to 0 °C, a lot below.
Open-circuit voltage is the chemistry’s promise, nearly untouched by cold. Internal resistance is how fast it keeps that promise. Hence the diagnosis of target 7, which movement of charge is hindered, and where: not the electrons, the ions; not the wire, the electrolyte and its surface.
The measurement that settles it: open-circuit voltage, then voltage under load, the difference divided by the current. At rest, the probes reach the pack’s blades; under load, the tool covers them: you need an adapter, two thin copper strips between pack and tool, with a loop of wire for the clamp meter. The meter’s MIN/MAX catches the start-up peak; otherwise, steady state, impeller unloaded, 10 to 15 A. Without an adapter, the sister experiment proves it on a single 18650.
What next?
- The battery in the freezer: the same question, measured on an AA.
- 1.1 Charge and its motion: the cell, ions inside, electrons outside.
- 6.2 The pack: the BMS that cuts out, charging in the cold.
The EGO pack opened
Ten groups, the nickel strips, the BMS.
storyElectricity before Franklin
Before it was something you measure, electricity was a parlour curiosity for two thousand years.
storyThe Leyden jar
If electricity is a fluid, you ought to be able to bottle it.
storyFranklin’s fluid
A multimeter in series shows a number with a sign, and the sign depends on which lead you put on which side.
storyGalvani’s frog
The pack of a cordless drill shows 3.7 V cells.
benchTwo nails in a glass of water
We think water conducts.
benchThe pencil lead and the lighter
We think heat gets in the way of everything that conducts: the hot contact resists more.
benchThe battery in the freezer
We think the cold drains the battery: the flashlight dies in January and comes back to life in the house.
questionWhy does a contact get hot?
The bike, after a climb: the pack cable is cool, but the XT60 that joins it to the controller is warm, its nylon browned on one side.
the crossroads1.1 Charge and its movement
Everything tied to this idea, and the exercises.